Saturday, September 20, 2014

James Dewar and the Liquefaction of Gases

Sir James Dewar (1842-1923)
On September 1842, Scottish chemist and physicist Sir James Dewar was born. He is probably best-known today for his invention of the Dewar flask, which he used in conjunction with extensive research into the liquefaction of gases.

James Dewar was born in Kincardine, Fife, Scotland, in 1842, the youngest of six boys. He lost his parents at the age of 15. He was educated at Dollar Academy and the University of Edinburgh, where he studied under Lord Playfair, a famous Scottish scientist and Liberal politician, whose assistant he later became. Dewar would also study under August Kekulé at Ghent. In 1875, Dewar was elected Jacksonian professor of natural experimental philosophy at the University of Cambridge and became a member of the Royal Institution. In 1877, he replaced Dr. John Hall Gladstone in the role of Fullerian Professor of Chemistry in 1877. Dewar was also the President of the Chemical Society in 1897 and the British Association for the Advancement of Science in 1902, as well as serving on the Royal Commission established to examine London's water supply from 1893 to 1894 and the Committee on Explosives. It was whilst he was serving on the Committee on Explosives that he and Frederick Augustus Abel developed cordite, a smokeless gunpowder alternative.

Dewar's scientific work covers a wide field and his earlier papers cover a wide range of topics; organic chemistry, Hydrogen and its physical constants, high temperature research, the temperature of the sun and of the electric spark, electro-photometry and the chemistry of the electric arc. In 1867 he described several chemical formulas for benzene. Ironically, one of the formulae, which does not represent benzene correctly and was not advocated by Dewar, is sometimes still called Dewar benzene. Dewar investigated the physiological action of light, and examined the changes which take place in the electrical condition of the retina under its influence. In 1878 a long series of spectroscopic observations, the later of which were devoted to the spectroscopic examination of various gaseous elements separated from atmospheric air by the aid of low temperatures.

Dewar is most widely known in connection with his work on the liquefaction of the so-called permanent gases and his researches at temperatures approaching absolute zero. In 1877, Louis Cailletet and Raoul Pictet independently were able to create small amounts of oxygen and nitrogen in liquid form at temperatures less than 80° above absolute zero, a feat even Michael Faraday, who had liquified most of the known gases by 1845, had been unable to carry out.[1]

In 1878 he devoted a Friday evening lecture at the Royal Institution to the then recent work of Cailletet and Pictet, and exhibited for the first time in Great Britain the working of the Cailletet apparatus. Six years later, again at the Royal Institution, he described the researches of Zygmunt Florenty Wróblewski and Karol Olszewski, and illustrated for the first time in public the liquefaction of oxygen and air. Soon afterwards he built a machine from which the liquefied gas could be drawn off through a valve for use as a cooling agent, before using the liquid oxygen in research work related to meteorites; about the same time he also obtained oxygen in the solid state.

The greatest stumbling block he encountered in his work with liquification was keeping the gases cold long enough to study them. Liquid oxygen kept in a flask absorbed heat from the surrounding air and returned to its gaseous phase. To eliminate the effect of the warm air, Dewar put the flask of liquid gas inside a larger flask and created a vacuum between them. A vacuum would prevent the transfer of energy that occurred through conduction or convection; heat would not penetrate and cold would not escape. To eliminate the transfer of radiant energy, Dewar silvered the walls of the flasks so they would reflect, rather than absorb, energy. He also invented a technique to create a more efficient vacuum.[1] Dewar found that charcoal eats gas at low temperatures. So he placed a bit of charcoal in the gap; then evacuated it as best he could. When cold liquid gas filled the tank, the charcoal removed the remaining air from the wall space, and made the insulation nearly perfect.[2]

James Dewar died in London in 1923, still holding the office of Fullerian Professor of Chemistry at the Royal Institution, having refused to retire.

At yovisto, you can earn a better understanding of temperature in the laws of physics and chemistry in the lecture of Prof. Gerbrand Ceder from Massachussetts Institute of Technology on Atomistic Computer Modeling of Materials.



References and Further Reading:
Related Articles in the Blog:


If you like the daily blog posts of yovisto about the history of science, please support us by clicking on the amazon links and making your next amazon purchase via our offered links. Nevertheless, please do also support your local (real world) bookstore at the corner of the street.
Post a Comment